Issue 42, 2009
From the journal:

Chemical Communications

From NHC→germylenes to stable NHC→germanone complexes†

Shenglai Yao,a   Yun Xionga  and  Matthias Driess*a  

* Corresponding authors

a Technische Universität Berlin, Institute of Chemistry: Metalorganics and Inorganic Materials, Sekr. C2, Strasse des 17. Juni 135, D-10623 Berlin, Germany
E-mail: matthias.driess@tu-berlin.de
Fax: +49 (0)30-314-29732
Tel: +49 (0)30-314-29731

Abstract

The unique isolable N-heterocyclic carbene (NHC)→germanone complexes 3a and 3b were synthesised and structurally characterised, starting from the corresponding NHC–germylene precursors 2a and 2b through straightforward oxygenation with N2O.

Graphical abstract: From NHC→germylenes to stable NHC→germanone complexes

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Article information

DOI
https://doi.org/10.1039/B914060C
Article type
Communication
Submitted
14 Jul 2009
Accepted
21 Aug 2009
First published
08 Sep 2009

Chem. Commun., 2009, 6466-6468

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From NHC→germylenes to stable NHC→germanone complexes

S. Yao, Y. Xiong and M. Driess, Chem. Commun., 2009, 6466 DOI: 10.1039/B914060C

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