Issue 37, 2009
From the journal:

Chemical Communications

Observation of reaction intermediates and kinetic mistakes in a remarkably slow self-assembly reaction†

Virginia M. Cangelosi,a   Timothy G. Carter,a   Lev N. Zakharova  and  Darren W. Johnson*a  

* Corresponding authors

a Department of Chemistry and Materials Science Institute, University of Oregon, and the Oregon Nanoscience and Microtechnologies Institute (ONAMI), Eugene, USA
E-mail: dwj@uoregon.edu
Fax: +1-541-346-0487
Tel: +1-541-346-1695

Abstract

Several intermediates and oligomeric mistakes in a metal–ligand self-assembly reaction are identified by 1H NMR, MALDI-MS, and XRD, providing evidence in support of multiple pathways in the “free-for-all” self-assembly process.

Graphical abstract: Observation of reaction intermediates and kinetic mistakes in a remarkably slow self-assembly reaction

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Article information

DOI
https://doi.org/10.1039/B914750K
Article type
Communication
Submitted
21 Jul 2009
Accepted
01 Aug 2009
First published
20 Aug 2009

Chem. Commun., 2009, 5606-5608

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Observation of reaction intermediates and kinetic mistakes in a remarkably slow self-assembly reaction

V. M. Cangelosi, T. G. Carter, L. N. Zakharov and D. W. Johnson, Chem. Commun., 2009, 5606 DOI: 10.1039/B914750K

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