Organometallic wheels based on coinage metal ions and norbornene: syntheses and structural characterization of [M(norbornene)3][SbF6] (M = Au, Ag, Cu)

Mauro Fianchini; Huixiong Dai; H. V. Rasika Dias

doi:10.1039/B915076E

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Organometallic wheels based on coinage metal ions and norbornene: syntheses and structural characterization of [M(norbornene)₃][SbF₆] (M = Au, Ag, Cu)†

Mauro Fianchini,^a Huixiong Dai^a and H. V. Rasika Dias*^a

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* Corresponding authors

^a Department of Chemistry and Biochemistry, The University of Texas at Arlington, Arlington, Texas 76019-0065, USA
E-mail: dias@uta.edu

Abstract

Three closely related organometallic “spoke–wheel” complexes featuring coinage metal ions, Au(I), Ag(I), and Cu(I), bonded to three norbornene molecules in trigonal planar fashion have been isolated and completely characterized using several methods including X-ray crystallography.

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Article information

DOI: https://doi.org/10.1039/B915076E
Article type: Communication
Submitted: 24 Jul 2009
Accepted: 16 Sep 2009
First published: 28 Sep 2009

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Chem. Commun., 2009, 6373-6375

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Organometallic wheels based on coinage metal ions and norbornene: syntheses and structural characterization of [M(norbornene)₃][SbF₆] (M = Au, Ag, Cu)

M. Fianchini, H. Dai and H. V. R. Dias, Chem. Commun., 2009, 6373 DOI: 10.1039/B915076E

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Chemical Communications