Issue 45, 2009

Umpolung of halide reactivity: efficient (diacetoxyiodo)benzene-mediated electrophilic α-halogenation of 1,3-dicarbonyl compounds

Abstract

An efficient high-yielding (diacetoxyiodo)benzene-mediated α-halogenation of 1,3-dicarbonyl compounds utilising titanium tetrahalides as the halide source has been developed.

Graphical abstract: Umpolung of halide reactivity: efficient (diacetoxyiodo)benzene-mediated electrophilic α-halogenation of 1,3-dicarbonyl compounds

Supplementary files

Article information

Article type
Communication
Submitted
29 Jul 2009
Accepted
22 Sep 2009
First published
12 Oct 2009

Chem. Commun., 2009, 6991-6993

Umpolung of halide reactivity: efficient (diacetoxyiodo)benzene-mediated electrophilic α-halogenation of 1,3-dicarbonyl compounds

R. Akula, M. Galligan and H. Ibrahim, Chem. Commun., 2009, 6991 DOI: 10.1039/B915348A

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