Borylene-based functionalization of Pt–alkynyl complexes by photochemical borylene transfer from [(OC)5Cr![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
BN(SiMe3)2]†
Abstract
Photochemical borylene transfer from [(OC)5CrBN(SiMe3)2] to the platinum σ-alkynyl complex [Cl(PMe3)2Pt–C![[triple bond, length as m-dash]](https://www.rsc.org/images/entities/char_e002.gif)
CPh] gave facile access to the first transition metal–borirene complex. The title compound has been fully characterized in solution and by
![Graphical abstract: Borylene-based functionalization of Pt–alkynyl complexes by photochemical borylene transfer from [(OC)5Cr [[double bond, length as m-dash]] BN(SiMe3)2]](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=B915926F&imageInfo.ImageIdentifier.Year=2009)
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![[double bond, length as m-dash]](https://www.rsc.org/images/entities/h2_char_e001.gif)
BN(SiMe3)2]
