Issue 47, 2009
From the journal:

Chemical Communications

Facile syntheses of dissymmetric ferrocene-functionalized Lewis acids and acid–base pairs†

Ian R. Morgan,ab   Angela Di Paolo,a   Dragoslav Vidovic,a   Ian A. Fallisb  and  Simon Aldridge*a  

* Corresponding authors

a Inorganic Chemistry Laboratory, South Parks Road, Oxford, UK
E-mail: Simon.Aldridge@chem.ox.ac.uk
Fax: +44 (0)1865 272690
Tel: +44 (0)1865 285201

b Cardiff School of Chemistry, Main Building, Park Place, Cardiff, UK
E-mail: fallis@cf.ac.uk
Fax: +44 (0)2920 874030
Tel: +44 (0)2920 875976

Abstract

A facile synthetic approach is reported for the synthesis of dissymmetric 1,2-ferrocenediyl Lewis acids and mixed acid–base pairs including the first example of a 1-phosphino-2-borylferrocene; the use of non-racemic electrophiles allows for the isolation of single diastereomer products.

Graphical abstract: Facile syntheses of dissymmetric ferrocene-functionalized Lewis acids and acid–base pairs

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Article information

DOI
https://doi.org/10.1039/B917304H
Article type
Communication
Submitted
21 Aug 2009
Accepted
26 Oct 2009
First published
04 Nov 2009

Chem. Commun., 2009, 7288-7290

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Facile syntheses of dissymmetric ferrocene-functionalized Lewis acids and acid–base pairs

I. R. Morgan, A. Di Paolo, D. Vidovic, I. A. Fallis and S. Aldridge, Chem. Commun., 2009, 7288 DOI: 10.1039/B917304H

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