A photoluminescent interpenetrating diamondoid metal–organic framework based on Cu4I4clusters with high thermal stability

Shi-Bin Ren; Le Zhou; Jun Zhang; Yi-Zhi Li; Hong-Bin Du; Xiao-Zeng You

doi:10.1039/B906905D

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A photoluminescent interpenetrating diamondoid metal–organic framework based on Cu₄I₄clusters with high thermal stability†

Shi-Bin Ren,^a Le Zhou,^a Jun Zhang,^a Yi-Zhi Li,^a Hong-Bin Du*^a and Xiao-Zeng You^a

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* Corresponding authors

^a State Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, China
E-mail: hbdu@nju.edu.cn

Abstract

A new, triply-interpenetrating diamondoid metal–organic framework, which exhibits strong photoluminescence at room temperature and high thermal stability, was prepared by the self-assembly of tetrahedral quadridentate linker tetrakis(4-pyridyloxymethylene)methane and tetrahedral Cu₄I₄clusters under solvothermal conditions.

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Article information

DOI: https://doi.org/10.1039/B906905D
Article type: Communication
Submitted: 06 Apr 2009
Accepted: 11 Jun 2009
First published: 01 Jul 2009

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CrystEngComm, 2009,11, 1834-1836

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A photoluminescent interpenetrating diamondoid metal–organic framework based on Cu₄I₄clusters with high thermal stability

S. Ren, L. Zhou, J. Zhang, Y. Li, H. Du and X. You, CrystEngComm, 2009, 11, 1834 DOI: 10.1039/B906905D

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