Issue 3, 2009
From the journal:

Soft Matter

Covalent and orthogonal multi-functionalization of terpolymers

Si Kyung Yangab  and  Marcus Weck*b  

* Corresponding authors

a School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, GA, USA

b Department of Chemistry and Molecular Design Institute, New York University, New York, NY, USA
E-mail: marcus.weck@nyu.edu
Fax: +212 995 4895
Tel: +212 992 7968

Abstract

Random poly(norbornene)-based terpolymers containing azide, ketone and maleimide functionalities along the side-chain were synthesized using ring-opening metathesis polymerization. Subsequent side-chain functionalizations were carried out using three distinct reactions: maleimide–thiol coupling, 1,3-dipolar cycloaddition, and hydrazone formation. All investigated functionalization transformations proceed with high fidelity and absolute selectivity under mild reaction conditions.

Graphical abstract: Covalent and orthogonal multi-functionalization of terpolymers

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Article information

DOI
https://doi.org/10.1039/B813675K
Article type
Paper
Submitted
06 Aug 2008
Accepted
16 Oct 2008
First published
21 Nov 2008

Soft Matter, 2009,5, 582-585

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Covalent and orthogonal multi-functionalization of terpolymers

S. K. Yang and M. Weck, Soft Matter, 2009, 5, 582 DOI: 10.1039/B813675K

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