Issue 11, 2010
From the journal:

Chemical Communications

Supported N-alkylimidazole-decorated dendrons as heterogeneous catalysts for the Baylis–Hillman reaction†

Kerem Gorena  and  Moshe Portnoy*a  

* Corresponding authors

a School of Chemistry, Raymond and Beverly Sackler Faculty of Exact Sciences, Tel Aviv University, Tel Aviv, Israel
E-mail: portnoy@post.tau.ac.il
Fax: +972-3-6409293
Tel: +972-3-6406517

Abstract

The Baylis–Hillman reaction between methyl vinyl ketone and aromatic aldehydes, catalyzed by N-alkylated imidazoles immobilized on polystyrene via dipolar cycloaddition, esterification or nucleophilic substitution, exhibits a remarkable positive dendritic effect.

Graphical abstract: Supported N-alkylimidazole-decorated dendrons as heterogeneous catalysts for the Baylis–Hillman reaction

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Article information

DOI
https://doi.org/10.1039/B915577E
Article type
Communication
Submitted
30 Jul 2009
Accepted
18 Dec 2009
First published
19 Jan 2010

Chem. Commun., 2010,46, 1965-1967

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Supported N-alkylimidazole-decorated dendrons as heterogeneous catalysts for the Baylis–Hillman reaction

K. Goren and M. Portnoy, Chem. Commun., 2010, 46, 1965 DOI: 10.1039/B915577E

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