Issue 1, 2010
From the journal:

Chemical Communications

Enhanced acyl radical formation in the Au nanoparticle-catalysed aldehydeoxidation†

Marco Conte,a   Hiroyuki Miyamura,b   Shū Kobayashib  and  Victor Chechik*a  

* Corresponding authors

a Department of Chemistry, University of York, Heslington, York, UK
E-mail: vc4@york.ac.uk
Tel: +44 1904 434185

b Graduate School of Pharmaceutical Sciences, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, Japan

Abstract

EPR spectroscopy and spin-trapping experiments showed that polymer-encapsulated Au nanoparticles promote aldehydeoxidationvia a radical pathway by initiating formation of acyl radicals.

Graphical abstract: Enhanced acyl radical formation in the Au nanoparticle-catalysed aldehydeoxidation

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Article information

DOI
https://doi.org/10.1039/B918200D
Article type
Communication
Submitted
04 Sep 2009
Accepted
07 Oct 2009
First published
19 Oct 2009

Chem. Commun., 2010,46, 145-147

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Enhanced acyl radical formation in the Au nanoparticle-catalysed aldehydeoxidation

M. Conte, H. Miyamura, S. Kobayashi and V. Chechik, Chem. Commun., 2010, 46, 145 DOI: 10.1039/B918200D

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