Issue 6, 2010

Reversible complexation of isocyanides by the distannyneAr′SnSnAr′ (Ar′ = C6H3-2,6(C6H3-2,6-iPr2)2)

Abstract

The reaction of the distannyne Ar′SnSnAr′ (Ar′ = C6H3-2,6(C6H3-2,6-iPr2)2) with tert-butyl or mesityl isocyanide afforded the bis-adducts Ar′SnSnAr′(CNBut)2 or Ar′SnSnAr′ (CNMes)2 in which the isonitriles are reversibly bound under ambient conditions.

Graphical abstract: Reversible complexation of isocyanides by the distannyne Ar′SnSnAr′ (Ar′ = C6H3-2,6(C6H3-2,6-iPr2)2)

Supplementary files

Article information

Article type
Communication
Submitted
23 Sep 2009
Accepted
07 Dec 2009
First published
08 Jan 2010

Chem. Commun., 2010,46, 943-945

Reversible complexation of isocyanides by the distannyne Ar′SnSnAr′ (Ar′ = C6H3-2,6(C6H3-2,6-iPr2)2)

Y. Peng, X. Wang, J. C. Fettinger and P. P. Power, Chem. Commun., 2010, 46, 943 DOI: 10.1039/B919828H

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