Issue 4, 2010
From the journal:

Chemical Communications

Expedient access to branched allylic silanes by copper-catalysed allylic substitution of linear allylic halides†

Devendra J. Vyasa  and  Martin Oestreich*a  

* Corresponding authors

a Organisch-Chemisches Institut, Westfälische Wilhelms-Universität, Corrensstrasse 40, D-48149 Münster, Germany
E-mail: martin.oestreich@uni-muenster.de
Fax: +49 (0)251 83-36501
Tel: +49 (0)251 83-33271

Abstract

An unprecedented copper-catalysed allylic transposition enables the regioselective synthesis of branched allylic silanes from linear allylic halides through direct C–Si bond formation.

Graphical abstract: Expedient access to branched allylic silanes by copper-catalysed allylic substitution of linear allylic halides

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Article information

DOI
https://doi.org/10.1039/B920793G
Article type
Communication
Submitted
07 Oct 2009
Accepted
25 Nov 2009
First published
11 Dec 2009

Chem. Commun., 2010,46, 568-570

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Expedient access to branched allylic silanes by copper-catalysed allylic substitution of linear allylic halides

D. J. Vyas and M. Oestreich, Chem. Commun., 2010, 46, 568 DOI: 10.1039/B920793G

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