Issue 11, 2010
From the journal:

Chemical Communications

Brilliant reversible luminescent mechanochromism of silver(i) complexes containing o-bis(diphenylphosphino)benzene and phosphinesulfide†

Toshiaki Tsukuda,*a   Marina Kawase,a   Ayumi Dairiki,a   Kenji Matsumotoa  and  Taro Tsubomura*a  

* Corresponding authors

a Seikei University, Department of Materials and Life Science, 3-3-1 Kichijoji-Kitamachi, Musashino, Tokyo, Japan
E-mail: tsukuda@st.seikei.ac.jp, tsubomura@st.seikei.ac.jp

Abstract

The Ag(I) complex with o-bis(diphenylphosphino)benzene shows reversible interconversion between blue-emitting (1b) and green-emitting (1g) materials on grinding and heating; comparison of the structure of 1b with another green-emitting crystals (2) having the same formula suggests the chromism results from intermolecular interactions between adjacent phenylene rings.

Graphical abstract: Brilliant reversible luminescent mechanochromism of silver(i) complexes containing o-bis(diphenylphosphino)benzene and phosphinesulfide

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Article information

DOI
https://doi.org/10.1039/B921111J
Article type
Communication
Submitted
12 Oct 2009
Accepted
04 Jan 2010
First published
15 Jan 2010

Chem. Commun., 2010,46, 1905-1907

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Brilliant reversible luminescent mechanochromism of silver(I) complexes containing o-bis(diphenylphosphino)benzene and phosphinesulfide

T. Tsukuda, M. Kawase, A. Dairiki, K. Matsumoto and T. Tsubomura, Chem. Commun., 2010, 46, 1905 DOI: 10.1039/B921111J

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