Issue 15, 2010
From the journal:

Chemical Communications

Hydrogen release from amminelithium borohydride, LiBH4·NH3†

Yanhui Guo,a   Guanglin Xia,a   Yihan Zhu,b   Liang Gaoa  and  Xuebin Yu*a  

* Corresponding authors

a Department of Materials Science, Fudan University, Shanghai, China
E-mail: yuxuebin@fudan.edu.cn
Fax: +8621 6564 3685
Tel: +8621 5566 4581

b Institute of Catalysis, Zhejiang University, Hangzhou 310000, China

Abstract

Amminelithium borohydride, LiBH4·NH3 which has two temperature sensitive chemical bonds N:→Li+ and N–H⋯H–B, is shown to release hydrogen at low temperatures by stabilizing the ammonia and promoting the recombination of the NH⋯HB bond.

Graphical abstract: Hydrogen release from amminelithium borohydride, LiBH4·NH3

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Article information

DOI
https://doi.org/10.1039/B924057H
Article type
Communication
Submitted
18 Nov 2009
Accepted
12 Jan 2010
First published
04 Feb 2010

Chem. Commun., 2010,46, 2599-2601

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Hydrogen release from amminelithium borohydride, LiBH4·NH3

Y. Guo, G. Xia, Y. Zhu, L. Gao and X. Yu, Chem. Commun., 2010, 46, 2599 DOI: 10.1039/B924057H

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