Issue 11, 2010
From the journal:

Chemical Communications

Complementary halogen and hydrogen bonding: sulfur⋯iodine interactions and thioamide ribbons†

Hadi D. Arman,a   Rebecca L. Gieseking,b   Timothy W. Hanksb  and  William T. Pennington*a  

* Corresponding authors

a Department of Chemistry, Clemson University, Clemson, SC, USA
E-mail: billp@clemson.edu
Fax: +1 864-656-6613
Tel: +1 864-656-4200

b Department of Chemistry, Furman University, Greenville, SC, USA
E-mail: tim.hanks@furman.edu
Fax: +1 864-294-3559
Tel: +1 864-294-3373

Abstract

Complementary halogen bonding and hydrogen bonding coexist in co-crystals of organoiodines with molecules containing the thioamide functionality. Thiourea·organoiodine co-crystals are shown to exhibit a remarkably reliable synthon with complementary N–H⋯S ribbons and S⋯I interactions.

Graphical abstract: Complementary halogen and hydrogen bonding: sulfur⋯iodine interactions and thioamide ribbons

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Article information

DOI
https://doi.org/10.1039/B925710A
Article type
Communication
Submitted
09 Dec 2009
Accepted
13 Jan 2010
First published
12 Feb 2010

Chem. Commun., 2010,46, 1854-1856

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Complementary halogen and hydrogen bonding: sulfur⋯iodine interactions and thioamide ribbons

H. D. Arman, R. L. Gieseking, T. W. Hanks and W. T. Pennington, Chem. Commun., 2010, 46, 1854 DOI: 10.1039/B925710A

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