Novel epothilone lactones by an unusual diversion of the Grubbs'metathesis reaction†
Abstract
An unusual reaction with Grubbs' catalyst during the synthesis of bridged epothilones yielded five-membered internal lactones instead of the expected
* Corresponding authors
a
Department of Chemistry, M/C 0212, Virginia Polytechnic Institute and State University, Blacksburg, USA
E-mail:
dkingston@vt.edu
Fax: +1 540 231 3255
Tel: +1 540 231 6570
b
Department of Chemistry, Emory University, Atlanta, USA
E-mail:
jsnyder@emory.edu
c Department of Chemistry, State University of New York of Binghamton, Binghamton, USA
An unusual reaction with Grubbs' catalyst during the synthesis of bridged epothilones yielded five-membered internal lactones instead of the expected
Q. Chen, T. Ganesh, Y. Jiang, A. Banerjee, S. Sharma, S. Bane, J. P. Snyder and D. G. I. Kingston, Chem. Commun., 2010, 46, 2019 DOI: 10.1039/B926174E
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