Issue 18, 2010
From the journal:

Chemical Communications

A water-soluble iridium(iii) porphyrin†

Hironobu Kanemitsu,a   Ryosuke Haradab  and  Seiji Ogo*abc  

* Corresponding authors

a Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan
E-mail: ogotcm@ mail.cstm.kyushu-u.ac.jp
Fax: +81-92-802-3307
Tel: +81-92-802-2821

b Centre for Future Chemistry, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan

c Core Research for Evolutional Science and Technology (CREST), Japan Science and Technology Agency (JST), Kawaguchi Centre Building, 4-1-8 Honcho, Kawaguchi-shi, Saitama 332-0012, Japan

Abstract

This work reports the synthesis and characterization of the first water-soluble iridium porphyrin, iridium(III) diaqua porphyrin [IrIII(TSPP)(OH2)2]3− (1, TSPP = tetra-p-sulfonatophenyl porphyrin). The structure of 1 was unequivocally determined by single crystal X-ray analysis. Benzo-18-crown-6-ether is essential for producing single crystals suitable for X-ray analysis.

Graphical abstract: A water-soluble iridium(iii) porphyrin

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Article information

DOI
https://doi.org/10.1039/C000263A
Article type
Communication
Submitted
06 Jan 2010
Accepted
18 Mar 2010
First published
30 Mar 2010

Chem. Commun., 2010,46, 3083-3085

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A water-soluble iridium(III) porphyrin

H. Kanemitsu, R. Harada and S. Ogo, Chem. Commun., 2010, 46, 3083 DOI: 10.1039/C000263A

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