Issue 14, 2010
From the journal:

Chemical Communications

Improved dynamics and positional bias with a second generation palladium(ii)-complexed molecular shuttle†

David A. Leigh,*a   Paul J. Lusby,*a   Roy T. McBurneya  and  Mark D. Symesa  

* Corresponding authors

a School of Chemistry, University of Edinburgh, King's Buildings, West Mains Road, Edinburgh, UK
E-mail: David.Leigh@ed.ac.uk, Paul.Lusby@ed.ac.uk
Fax: +44 (0)131-650-6453
Tel: +44 (0)131-650-4721

Abstract

A second generation palladium(II)-complexed molecular shuttle, featuring structural changes to the size and shape of the macrocycle, shows significantly increased rates of shuttling and improved co-conformational bias compared to the original system.

Graphical abstract: Improved dynamics and positional bias with a second generation palladium(ii)-complexed molecular shuttle

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Article information

DOI
https://doi.org/10.1039/C001697G
Article type
Communication
Submitted
27 Jan 2010
Accepted
22 Feb 2010
First published
05 Mar 2010

Chem. Commun., 2010,46, 2382-2384

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Improved dynamics and positional bias with a second generation palladium(II)-complexed molecular shuttle

D. A. Leigh, P. J. Lusby, R. T. McBurney and M. D. Symes, Chem. Commun., 2010, 46, 2382 DOI: 10.1039/C001697G

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