Issue 21, 2010
From the journal:

Chemical Communications

Remarkable rate acceleration of [4 + 2] cyclodimerization of an ethynylanthracene derivative on the product crystal surfaces†

Junpei Yuasa,*a   Takuya Ogawaa  and  Tsuyoshi Kawai*a  

* Corresponding authors

a 8916-5 Takayama, Ikoma, Nara 630-0192, Japan
E-mail: tkawai@ms.naist.jp, yuasaj@ms.naist.jp
Fax: (+81) 743-72-6179

Abstract

Slow evaporation of a chloroform–n-hexane solution of 2-(anthracene-9-ylethynyl)-1-methylbenzimidazole (BzIm–An) yields cyclodimer (BzIm–An)2 as crystals; the cyclodimerization is then dramatically accelerated on the product crystal faces.

Graphical abstract: Remarkable rate acceleration of [4 + 2] cyclodimerization of an ethynylanthracene derivative on the product crystal surfaces

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Article information

DOI
https://doi.org/10.1039/C002103B
Article type
Communication
Submitted
01 Feb 2010
Accepted
22 Mar 2010
First published
16 Apr 2010

Chem. Commun., 2010,46, 3693-3695

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Remarkable rate acceleration of [4 + 2] cyclodimerization of an ethynylanthracene derivative on the product crystal surfaces

J. Yuasa, T. Ogawa and T. Kawai, Chem. Commun., 2010, 46, 3693 DOI: 10.1039/C002103B

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