Issue 23, 2010
From the journal:

Chemical Communications

Silica gel-mediated rearrangement of allylic acetates. Application to the synthesis of 1,3-enynes†

Anna Serra-Muns,a   Amandine Guérinot,a   Sébastien Reymond*a  and  Janine Cossy*a  

* Corresponding authors

a Laboratoire de Chimie Organique, ESPCI ParisTech, UMR CNRS 7084, 10, rue Vauquelin, 75231 Paris Cedex 05, France
E-mail: sebastien.reymond@espci.fr, janine.cossy@espci.fr
Fax: (+33)140794660
Tel: (+33)140794659

Abstract

Silica gel was found to efficiently promote the rearrangement of allylic acetates into their most stable regioisomers under microwave irradiation. The reaction is easy to perform and eco-friendly. This method was applied to the metal-free synthesis of 1,3-enynes.

Graphical abstract: Silica gel-mediated rearrangement of allylic acetates. Application to the synthesis of 1,3-enynes

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Article information

DOI
https://doi.org/10.1039/C0CC00035C
Article type
Communication
Submitted
19 Feb 2010
Accepted
09 Apr 2010
First published
12 May 2010

Chem. Commun., 2010,46, 4178-4180

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Silica gel-mediated rearrangement of allylic acetates. Application to the synthesis of 1,3-enynes

A. Serra-Muns, A. Guérinot, S. Reymond and J. Cossy, Chem. Commun., 2010, 46, 4178 DOI: 10.1039/C0CC00035C

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