Issue 26, 2010
From the journal:

Chemical Communications

The coordination preferences of metal centres modulate superexchange coupling interactions in a metallo-supramolecular helical assembly†

Rosa Pedrido,*a   Miguel Vázquez López,*a   Lorenzo Sorace,b   Ana M. González-Noya,c   Magdalena Cwiklinska,a   Vanesa Suárez-Gómez,a   Guillermo Zaragozad  and  Manuel R. Bermejoa  

* Corresponding authors

a Departamento de Química Inorgánica, Facultad de Química, Universidad de Santiago de Compostela, 15782 Santiago de Compostela, Spain
E-mail: miguel.vazquez.lopez@usc.es, rosa.pedrido@usc.es

b Laboratory of Molecular Magnetism, Dipartimento di Chimica “Ugo Schiff” and UdR INSTM, Università di Firenze, 50019 Sesto Fiorentino (Fi), Italy

c Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Santiago de Compostela, 27002 Lugo, Spain

d Unidad de Difracción de Rayos X, Edificio CACTUS, Universidad de Santiago de Compostela, 15782 Santiago de Compostela, Spain

Abstract

A method to modulate the strength of the superexchange coupling interaction in dinuclear helical assemblies based on the coordination preferences of the metal centres is described.

Graphical abstract: The coordination preferences of metal centres modulate superexchange coupling interactions in a metallo-supramolecular helical assembly

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Article information

DOI
https://doi.org/10.1039/C0CC00338G
Article type
Communication
Submitted
11 Mar 2010
Accepted
30 Apr 2010
First published
27 May 2010

Chem. Commun., 2010,46, 4797-4799

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The coordination preferences of metal centres modulate superexchange coupling interactions in a metallo-supramolecular helical assembly

R. Pedrido, M. Vázquez López, L. Sorace, A. M. González-Noya, M. Cwiklinska, V. Suárez-Gómez, G. Zaragoza and M. R. Bermejo, Chem. Commun., 2010, 46, 4797 DOI: 10.1039/C0CC00338G

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