Issue 41, 2010
From the journal:

Chemical Communications

Facile synthesis of hypersilylated aromatic compounds by palladium-mediated arylation reaction†

Aldes Lesbani,‡a   Hitoshi Kondo,a   Jun-ichi Sato,a   Yoshinori Yamanoi*a  and  Hiroshi Nishihara*a  

* Corresponding authors

a Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
E-mail: yamanoi@chem.s.u-tokyo.ac.jp, nisihara@chem.s.u-tokyo.ac.jp
Fax: +81-3-5841-8063
Tel: +81-3-5841-4347

Abstract

The treatment of aryl iodides with tris(trimethylsilyl)silane in the presence of Pd(P(tBu)3)2 and the Hünig base leads to the formation of hypersilylated aromatic products in good to excellent yields without cleavage of weak Si–Si bonds under mild conditions.

Graphical abstract: Facile synthesis of hypersilylated aromatic compounds by palladium-mediated arylation reaction

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Article information

DOI
https://doi.org/10.1039/C0CC00352B
Article type
Communication
Submitted
12 Mar 2010
Accepted
02 Sep 2010
First published
24 Sep 2010

Chem. Commun., 2010,46, 7784-7786

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Facile synthesis of hypersilylated aromatic compounds by palladium-mediated arylation reaction

A. Lesbani, H. Kondo, J. Sato, Y. Yamanoi and H. Nishihara, Chem. Commun., 2010, 46, 7784 DOI: 10.1039/C0CC00352B

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