Issue 26, 2010
From the journal:

Chemical Communications

Using one spin-transition to trigger another in solid solutions of two different spin-crossover complexes†

Malcolm A. Halcrow*a  

* Corresponding authors

a School of Chemistry, University of Leeds, Woodhouse Lane, Leeds, UK
E-mail: m.a.halcrow@leeds.ac.uk
Fax: +44 (0)113 343 6565
Tel: +44 (0)113 343 6506

Abstract

Phase-pure solid solutions of [Co(terpy)2][BF4]2 and [M(bpp)2][BF4]2 (M = Fe or Ru, bpp = 2,6-dipyrazol-1-ylpyridine) have been prepared. The spin-state of the [Co(terpy)2]2+ dopant is modulated by the spin-state of the [Fe(bpp)2]2+ centres in the iron-containing materials.

Graphical abstract: Using one spin-transition to trigger another in solid solutions of two different spin-crossover complexes

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Article information

DOI
https://doi.org/10.1039/C0CC00603C
Article type
Communication
Submitted
26 Mar 2010
Accepted
17 May 2010
First published
03 Jun 2010

Chem. Commun., 2010,46, 4761-4763

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Using one spin-transition to trigger another in solid solutions of two different spin-crossover complexes

M. A. Halcrow, Chem. Commun., 2010, 46, 4761 DOI: 10.1039/C0CC00603C

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