Issue 25, 2010
From the journal:

Chemical Communications

Nanotubular non-covalent macrocycle within non-covalent macrocycleassembly: (MeOH)12 encapsulated in a molecular clipcyclododecamer†

Li-Ping Cao,a   Xiang-Gao Meng,a   Jiao-Yang Ding,a   Yun-Feng Chen,a   Meng Gao,a   Yan-Dong Wu,a   Yi-Tao Li,a   An-Xin Wu*ab  and  Lyle Isaacs*c  

* Corresponding authors

a Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, Central China Normal University, 152 Luoyu Road, Wuhan 430079, P. R. China
E-mail: chwuax@mail.ccnu.edu.cn
Fax: +86 027 67867129
Tel: +86 027 67867129

b Department of Chemistry, State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. China

c Department of Chemistry and Biochemistry, University of Maryland, College Park, USA
E-mail: lisaacs@umd.edu

Abstract

A noncovalent macrocycle-within-noncovalent macrocycle assembly is formed from twelve molecules of (±)-1 and twelve molecules of MeOH in the solid state. The H-bonded (MeOH)12 cyclododecamer assumes a crown-shaped geometry that has not previously been predicted theoretically or found experimentally.

Graphical abstract: Nanotubular non-covalent macrocycle within non-covalent macrocycle assembly: (MeOH)12 encapsulated in a molecular clip cyclododecamer

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Article information

DOI
https://doi.org/10.1039/C0CC00677G
Article type
Communication
Submitted
30 Mar 2010
Accepted
23 Apr 2010
First published
19 May 2010

Chem. Commun., 2010,46, 4508-4510

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Nanotubular non-covalent macrocycle within non-covalent macrocycle assembly: (MeOH)12 encapsulated in a molecular clip cyclododecamer

L. Cao, X. Meng, J. Ding, Y. Chen, M. Gao, Y. Wu, Y. Li, A. Wu and L. Isaacs, Chem. Commun., 2010, 46, 4508 DOI: 10.1039/C0CC00677G

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