Palladacycle containing nitrogen and selenium: highly active pre-catalyst for the Suzuki–Miyaura coupling reaction and unprecedented conversion into nano-sized Pd17Se15

Gyandshwar Kumar Rao; Arun Kumar; Jahangeer Ahmed; Ajai Kumar Singh

doi:10.1039/C0CC01075H

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Palladacycle containing nitrogen and selenium: highly active pre-catalyst for the Suzuki–Miyaura coupling reaction and unprecedented conversion into nano-sized Pd₁₇Se₁₅†

Gyandshwar Kumar Rao,^a Arun Kumar,^a Jahangeer Ahmed ‡^a and Ajai Kumar Singh*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, Indian Institute of Technology Delhi, New Delhi-110016, India
E-mail: aksingh@chemistry.iitd.ac.in, ajai57@hotmail.com
Fax: + 91 11 26581102
Tel: + 91 11 26591379

Abstract

Newly synthesized, air and moisture insensitive palladacycle [PdCl(L–H)] (L = (C₆H₅)(2-HOC₆H₄)CHNH(CH₂)₃SePh; a (N, Se, C⁻) ligand) shows high catalytic activity for the Suzuki–Miyaura coupling reaction of phenylboronic acid with aryl/heteroaryl chlorides/bromides (TON for aryl chlorides up to 9200) and is converted to ∼8 nm size particles of Pd₁₇Se₁₅ (probably the real catalyst).

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C0CC01075H
Article type: Communication
Submitted: 22 Apr 2010
Accepted: 21 Jun 2010
First published: 12 Jul 2010

Download Citation

Chem. Commun., 2010,46, 5954-5956

Permissions

Request permissions

Palladacycle containing nitrogen and selenium: highly active pre-catalyst for the Suzuki–Miyaura coupling reaction and unprecedented conversion into nano-sized Pd₁₇Se₁₅

G. K. Rao, A. Kumar, J. Ahmed and A. K. Singh, Chem. Commun., 2010, 46, 5954 DOI: 10.1039/C0CC01075H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications