Issue 34, 2010

Flexibility of cubane-like Cu4I4 framework: temperature dependence of molecular structure and luminescence thermochromism of [Cu4I4(PPh3)4] in two polymorphic crystalline states

Abstract

Multitemperature X-ray structure analyses and photoemission spectra of [Cu4I4(PPh3)4] in two polymorphic crystals reveal that the cubane-like framework is flexibly distorted effecting luminescence thermochromism.

Graphical abstract: Flexibility of cubane-like Cu4I4 framework: temperature dependence of molecular structure and luminescence thermochromism of [Cu4I4(PPh3)4] in two polymorphic crystalline states

Supplementary files

Article information

Article type
Communication
Submitted
17 May 2010
Accepted
25 Jun 2010
First published
29 Jul 2010

Chem. Commun., 2010,46, 6302-6304

Flexibility of cubane-like Cu4I4 framework: temperature dependence of molecular structure and luminescence thermochromism of [Cu4I4(PPh3)4] in two polymorphic crystalline states

H. Kitagawa, Y. Ozawa and K. Toriumi, Chem. Commun., 2010, 46, 6302 DOI: 10.1039/C0CC01434F

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