Issue 37, 2010
From the journal:

Chemical Communications

Ionic nature of Ge(ii)-centered dications: a germaniumK-edge X-ray absorption near edge structures study†

Matthew J. Ward,a   Paul A. Rupar,a   Michael W. Murphy,a   Yun-Mui Yiu,a   Kim M. Baines*a  and  T. K. Sham*a  

* Corresponding authors

a Department of Chemistry, University of Western Ontario, London, Ontario, Canada
E-mail: tsham@uwo.ca, kbaines2@uwo.ca

Abstract

Measurement of the ionic nature of [Ge(cryptand[2.2.2])]2+ by XANES has provided direct experimental evidence that the germanium center is best described as a nearly-naked dication encased within an electron rich cryptand cage.

Graphical abstract: Ionic nature of Ge(ii)-centered dications: a germanium K-edge X-ray absorption near edge structures study

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Article information

DOI
https://doi.org/10.1039/C0CC01925A
Article type
Communication
Submitted
17 Jun 2010
Accepted
22 Jul 2010
First published
25 Aug 2010

Chem. Commun., 2010,46, 7016-7018

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Ionic nature of Ge(II)-centered dications: a germanium K-edge X-ray absorption near edge structures study

M. J. Ward, P. A. Rupar, M. W. Murphy, Y. Yiu, K. M. Baines and T. K. Sham, Chem. Commun., 2010, 46, 7016 DOI: 10.1039/C0CC01925A

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