Issue 43, 2010
From the journal:

Chemical Communications

Decarboxylative homocoupling of (hetero)aromatic carboxylic acids†

Josep Cornella,a   Hicham Lahlalia  and  Igor Larrosa*a  

* Corresponding authors

a Queen Mary University of London, School of Biological and Chemical Sciences, Joseph Priestley Building, Mile End Road, London, UK
E-mail: i.larrosa@qmul.ac.uk
Fax: +44 (0)20 7882 7427
Tel: +44 (0)20 7882 8404

Abstract

A variety of hetero(aromatic) carboxylic acids are shown to undergo decarboxylative homocoupling, mediated by a Pd/Ag system. This novel methodology for the synthesis of symmetrical biaryls avoids the use of haloarenes and organometallic compounds as starting materials.

Graphical abstract: Decarboxylative homocoupling of (hetero)aromatic carboxylic acids

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Article information

DOI
https://doi.org/10.1039/C0CC01943G
Article type
Communication
Submitted
17 Jun 2010
Accepted
09 Sep 2010
First published
30 Sep 2010

Chem. Commun., 2010,46, 8276-8278

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Decarboxylative homocoupling of (hetero)aromatic carboxylic acids

J. Cornella, H. Lahlali and I. Larrosa, Chem. Commun., 2010, 46, 8276 DOI: 10.1039/C0CC01943G

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