Issue 41, 2010
From the journal:

Chemical Communications

Electronic effects in iridium C–H borylations: insights from unencumbered substrates and variation of boryl ligand substituents†

Britt A. Vanchura, II,a   Sean M. Preshlock,a   Philipp C. Roosen,a   Venkata A. Kallepalli,a   Richard J. Staples,a   Robert E. Maleczka, Jr.,*a   Daniel A. Singleton*b  and  Milton R. Smith, III*a  

* Corresponding authors

a Department of Chemistry, Michigan State University, East Lansing, Michigan 48824-1322, USA
E-mail: smithmil@msu.edu
Fax: 001 517-353-1793
Tel: 001 517-355-9715 x166

b Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, Texas 77842, USA
E-mail: singleton@mail.chem.tamu.edu

Abstract

Experiment and theory favour a model of C–H borylation where significant proton transfer character exists in the transition state.

Graphical abstract: Electronic effects in iridium C–H borylations: insights from unencumbered substrates and variation of boryl ligand substituents

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Article information

DOI
https://doi.org/10.1039/C0CC02041A
Article type
Communication
Submitted
23 Jun 2010
Accepted
24 Aug 2010
First published
20 Sep 2010

Chem. Commun., 2010,46, 7724-7726

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Electronic effects in iridium C–H borylations: insights from unencumbered substrates and variation of boryl ligand substituents

B. A. Vanchura, II, S. M. Preshlock, P. C. Roosen, V. A. Kallepalli, R. J. Staples, R. E. Maleczka, Jr., D. A. Singleton and M. R. Smith, III, Chem. Commun., 2010, 46, 7724 DOI: 10.1039/C0CC02041A

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