Issue 42, 2010
From the journal:

Chemical Communications

Cooperative spin crossover phenomena in [Fe(NH2trz)3](tosylate)2nanoparticles†

Alexey Tokarev,a   Lionel Salmon,a   Yannick Guari,b   William Nicolazzi,a   Gábor Molnára  and  Azzedine Bousseksou*a  

* Corresponding authors

a Laboratoire de Chimie de Coordination, CNRS UPR-8241 and Université de Toulouse, UPS, INP, F-31077 Toulouse, France
E-mail: azzedine.bousseksou@lcc-toulouse.fr
Fax: +33(0)561553003

b Institut Charles Gerhardt Montpellier, UMR5253, Chimie Moléculaire et Organisation du Solide, Université Montpellier II, Place E. Bataillon, Montpellier cedex 5, France

Abstract

Nanoparticles of the [Fe(NH2trz)3](tosylate)2 spin crossover complex of 3–4 nm size were synthesized and dispersed in a nonionic surfactant. This colloidal system exhibits thermal spin crossover phenomena associated with a virtually first order transition. By thermal treatment the colloidal suspension can be transformed into a fibrous structure forming a gel.

Graphical abstract: Cooperative spin crossover phenomena in [Fe(NH2trz)3](tosylate)2 nanoparticles

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C0CC02606A
Article type
Communication
Submitted
16 Jul 2010
Accepted
09 Sep 2010
First published
27 Sep 2010

Chem. Commun., 2010,46, 8011-8013

Permissions

Request permissions

Cooperative spin crossover phenomena in [Fe(NH2trz)3](tosylate)2 nanoparticles

A. Tokarev, L. Salmon, Y. Guari, W. Nicolazzi, G. Molnár and A. Bousseksou, Chem. Commun., 2010, 46, 8011 DOI: 10.1039/C0CC02606A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements