Issue 45, 2010

Design and synthesis of a novel three-hindered quadrant bisphosphine ligand and its application in asymmetric hydrogenation

Abstract

A novel three hindered quadrant bisphosphine ligand has been synthesized. The ligand shows excellent enantioselectivities and reactivities for rhodium-catalyzed hydrogenations of various functionalized olefins.

Graphical abstract: Design and synthesis of a novel three-hindered quadrant bisphosphine ligand and its application in asymmetric hydrogenation

Supplementary files

Article information

Article type
Communication
Submitted
16 Jul 2010
Accepted
17 Aug 2010
First published
14 Oct 2010

Chem. Commun., 2010,46, 8555-8557

Design and synthesis of a novel three-hindered quadrant bisphosphine ligand and its application in asymmetric hydrogenation

K. Huang, X. Zhang, T. J. Emge, G. Hou, B. Cao and X. Zhang, Chem. Commun., 2010, 46, 8555 DOI: 10.1039/C0CC02620D

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