Issue 43, 2010

Mechanism of visible-light photoisomerization of a rhenium(i) carbonyl–diimine complex

Abstract

The mechanism of photoisomerization of a ReI carbonyldiimine complex under visible-light irradiation is deciphered by means of ab initio calculations. By highlighting the key role of triplet states as well as spin–orbit and vibronic couplings, we provide a clear picture of this complicated multi-step process.

Graphical abstract: Mechanism of visible-light photoisomerization of a rhenium(i) carbonyl–diimine complex

Article information

Article type
Communication
Submitted
19 Jul 2010
Accepted
08 Sep 2010
First published
28 Sep 2010

Chem. Commun., 2010,46, 8225-8227

Mechanism of visible-light photoisomerization of a rhenium(I) carbonyl–diimine complex

E. Gindensperger, H. Köppel and C. Daniel, Chem. Commun., 2010, 46, 8225 DOI: 10.1039/C0CC02661A

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