Issue 42, 2010
From the journal:

Chemical Communications

Chain mechanism for exchange of D2 with a ruthenium hydride†‡

Charles P. Casey,*a   Jeffrey B. Johnson,a   Xiandong Jiao,a   Sharon E. Beetnera  and  Steven W. Singera  

* Corresponding authors

a Department of Chemistry, University of Wisconsin-Madison, 1101 University Avenue, Madison WI, USA
E-mail: casey@chem.wisc.edu
Fax: +1-608-265-4534
Tel: +1-608-262-0584

Abstract

The ruthenium hydride of (Ar4CpOH)Ru(CO)2H exchanges cleanly and rapidly with D2 at room temperature to generate the ruthenium deuteride. A chain mechanism is proposed to explain the much more rapid exchange of RuH/D2 than RuCO exchange with 13CO.

Graphical abstract: Chain mechanism for exchange of D2 with a ruthenium hydride

  • This article is part of the themed collection: Hydrogen
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Article information

DOI
https://doi.org/10.1039/C0CC02875D
Article type
Communication
Submitted
28 Jul 2010
Accepted
01 Sep 2010
First published
21 Sep 2010

Chem. Commun., 2010,46, 7915-7917

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Chain mechanism for exchange of D2 with a ruthenium hydride

C. P. Casey, J. B. Johnson, X. Jiao, S. E. Beetner and S. W. Singer, Chem. Commun., 2010, 46, 7915 DOI: 10.1039/C0CC02875D

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