Issue 41, 2010
From the journal:

Chemical Communications

Reactivity of alkynylzirconates towards allyl bromides: selective formation of β-allyl-zirconacyclopentadienes†‡

Xiaoyu Yan,a   Yiqing Zhoua  and  Chanjuan Xi*ab  

* Corresponding authors

a Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, China
E-mail: cjxi@tsinghua.edu.cn
Tel: +86-10-62782695

b State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China

Abstract

Reaction of alkynylzirconates with allyl bromides afforded β-allyl-zirconacyclopentadienes with high selectivity in unique reaction site.

Graphical abstract: Reactivity of alkynylzirconates towards allyl bromides: selective formation of β-allyl-zirconacyclopentadienes

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Article information

DOI
https://doi.org/10.1039/C0CC02997A
Article type
Communication
Submitted
03 Aug 2010
Accepted
06 Sep 2010
First published
20 Sep 2010

Chem. Commun., 2010,46, 7801-7803

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Reactivity of alkynylzirconates towards allyl bromides: selective formation of β-allyl-zirconacyclopentadienes

X. Yan, Y. Zhou and C. Xi, Chem. Commun., 2010, 46, 7801 DOI: 10.1039/C0CC02997A

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