Retro-reaction of singly bonded La@C82 derivatives

Yuta Takano; Midori O. Ishitsuka; Takahiro Tsuchiya; Takeshi Akasaka; Tatsuhisa Kato; Shigeru Nagase

doi:10.1039/C0CC03005H

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Retro-reaction of singly bonded La@C₈₂ derivatives†

Yuta Takano,^a Midori O. Ishitsuka,^a Takahiro Tsuchiya,^a Takeshi Akasaka,*^a Tatsuhisa Kato^b and Shigeru Nagase^c

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* Corresponding authors

^a Center for Tsukuba Advanced Research Alliance, University of Tsukuba, Ibaraki, Japan
E-mail: akasaka@tara.tsukuba.ac.jp
Fax: +81 29 853 6409
Tel: +81 29 853 6409

^b Institute for the Promotion of Excellence in Higher Education, Kyoto University, Kyoto, Japan

^c Department of Theoretical and Computational Molecular Science, Institute for Molecular Science, Okazaki, Aichi 444-8585, Japan

Abstract

Retro-reaction of radical monoadducts of a paramagnetic endohedral metallofullerene, La@C_2v-C₈₂, is shown using thermal reaction in the presence of a radical trapping reagent, affording pristine La@C_2v-C₈₂ in high yield (96%).

This article is part of the themed collection: Carbon nanostructures

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Supplementary files

Experimental procedure, HPLC profiles, MALDI-TOF Mass and EPR spectra of the reaction mixtures PDF (479K)

Article information

DOI: https://doi.org/10.1039/C0CC03005H
Article type: Communication
Submitted: 03 Aug 2010
Accepted: 07 Sep 2010
First published: 23 Sep 2010

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Chem. Commun., 2010,46, 8035-8036

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Retro-reaction of singly bonded La@C₈₂ derivatives

Y. Takano, M. O. Ishitsuka, T. Tsuchiya, T. Akasaka, T. Kato and S. Nagase, Chem. Commun., 2010, 46, 8035 DOI: 10.1039/C0CC03005H

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