Issue 40, 2010
From the journal:

Chemical Communications

Synthesis and coordination behaviors of P-stereogenic polymers†

Hiroaki Imoto,a   Yasuhiro Morisaki*a  and  Yoshiki Chujo*a  

* Corresponding authors

a Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan
E-mail: ymo@chujo.synchem.kyoto-u.ac.jp, chujo@chujo.synchem.kyoto-u.ac.jp

Abstract

Optically active polymers containing P-stereogenic bisphosphine and 1,2,3-triazole units in the main chain were obtained by copper-catalyzed Huisgen cycloaddition. The repeating unit of the polymer adopted bidentate as well as tetradentate coordination, leading to the change in the conformations of the polymer via complexation with transition metals.

Graphical abstract: Synthesis and coordination behaviors of P-stereogenic polymers

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Article information

DOI
https://doi.org/10.1039/C0CC03120H
Article type
Communication
Submitted
09 Aug 2010
Accepted
01 Sep 2010
First published
17 Sep 2010

Chem. Commun., 2010,46, 7542-7544

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Synthesis and coordination behaviors of P-stereogenic polymers

H. Imoto, Y. Morisaki and Y. Chujo, Chem. Commun., 2010, 46, 7542 DOI: 10.1039/C0CC03120H

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