Issue 46, 2010

Structural diversity through ligand flexibility: two novel metal–organic nets via ligand-to-ligand cross-linking of “paddlewheels”

Abstract

Solvothermal reaction of a partially flexible ligand, H4L, and Cu(NO3)2·2.5H2O afforded two cross-linked Kagomé lattices of formula [Cu2(L)]n: an acs net sustained by novel trigonal prismatic supermolecular building blocks (SBBs) and the first example of a partially pillared Kagomé net.

Graphical abstract: Structural diversity through ligand flexibility: two novel metal–organic nets via ligand-to-ligand cross-linking of “paddlewheels”

Supplementary files

Article information

Article type
Communication
Submitted
15 Aug 2010
Accepted
22 Sep 2010
First published
22 Oct 2010

Chem. Commun., 2010,46, 8734-8736

Structural diversity through ligand flexibility: two novel metal–organic nets via ligand-to-ligand cross-linking of “paddlewheels”

W. Qiu, J. A. Perman, Ł. Wojtas, M. Eddaoudi and M. J. Zaworotko, Chem. Commun., 2010, 46, 8734 DOI: 10.1039/C0CC03270K

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