Issue 45, 2010
From the journal:

Chemical Communications

New insights into the acid mediated disproportionation of pentavalent uranyl†

Victor Mougel,a   Biplab Biswas,a   Jacques Pécauta  and  Marinella Mazzanti*a  

* Corresponding authors

a Laboratoire de Reconnaissance Ionique et Chimie de Coordination, SCIB, (UMR-E 3 CEA-UJF FRE 3200 CNRS), INAC, CEA-Grenoble, 17 rue des Martyrs, 38054 Grenoble Cedex 09, France
E-mail: marinella.mazzanti@cea.fr
Fax: +33 4 38 78 5090
Tel: +33 4 3878 3955

Abstract

The reaction of benzoic acid with the uranyl(V) complex [(UO2Py5)(KI2Py2)] in pyridine leads to immediate disproportionation with formation of a hexanuclear U(IV) benzoate cluster, a bis-benzoate complex of uranyl(VI) and water.

Graphical abstract: New insights into the acid mediated disproportionation of pentavalent uranyl

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Article information

DOI
https://doi.org/10.1039/C0CC03443F
Article type
Communication
Submitted
24 Aug 2010
Accepted
01 Oct 2010
First published
18 Oct 2010

Chem. Commun., 2010,46, 8648-8650

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New insights into the acid mediated disproportionation of pentavalent uranyl

V. Mougel, B. Biswas, J. Pécaut and M. Mazzanti, Chem. Commun., 2010, 46, 8648 DOI: 10.1039/C0CC03443F

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