Issue 48, 2010
From the journal:

Chemical Communications

Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate: new methods for constructing porous materials†

Andrea N. Alsobrook,a   Brad G. Hauser,b   Joseph T. Hupp,b   Evgeny V. Alekseev,c   Wulf Depmeierc  and  Thomas E. Albrecht-Schmitt*a  

* Corresponding authors

a Department of Civil Engineering and Geological Sciences and Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556, USA
E-mail: talbrec1@nd.edu
Fax: +1 574-631-9236

b Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA

c Department of Crystallography, University of Kiel, Kiel, Germany

Abstract

Four heterobimetallic U(VI)/M(II) (M = Mn, Co, Cd) carboxyphosphonates have been synthesized. M2[(UO2)6(PO3CH2CO2)3O3(OH)(H2O)2]·16H2O (M = Mn(II), Co(II), and Cd(II)) adopt cubic three-dimensional network structures with large cavities approximately 16 Å in diameter that are filled with co-crystallized water molecules. [Cd3(UO2)6(PO3CH2CO2)6(H2O)13]·6H2O forms a rhombohedral channel structure with hydrated Cd(II) within the channels. The cubic compound (Co) displays differential gas absorption with a surface area for CO2 uptake of 40 m2 g−1 at 273 K, and no uptake of N2 at 77 K.

Graphical abstract: Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate: new methods for constructing porous materials

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Article information

DOI
https://doi.org/10.1039/C0CC03507F
Article type
Communication
Submitted
26 Aug 2010
Accepted
13 Oct 2010
First published
01 Nov 2010

Chem. Commun., 2010,46, 9167-9169

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Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate: new methods for constructing porous materials

A. N. Alsobrook, B. G. Hauser, J. T. Hupp, E. V. Alekseev, W. Depmeier and T. E. Albrecht-Schmitt, Chem. Commun., 2010, 46, 9167 DOI: 10.1039/C0CC03507F

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