Issue 47, 2010
From the journal:

Chemical Communications

Helical polymers based on intramolecularly hydrogen-bonded aromatic polyamides†

Yi-Xuan Lu,a   Zhu-Ming Shi,b   Zhan-Ting Li*b  and  Zhibin Guan*a  

* Corresponding authors

a Department of Chemistry, 1102 Natural Sciences 2, University of California, Irvine, USA
E-mail: zguan@uci.edu
Fax: +1 9498242210
Tel: +1 9498245172

b State Key Laboratory of Bioorganic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China
E-mail: ztli@mail.sioc.ac.cn
Fax: +86 21 64166128
Tel: +86 21 54925122

Abstract

Inspired by arylamide-based oligomeric foldermers that are stabilized by intramolecular hydrogen bonding, a series of polyamides with intramolecular hydrogen-bonding motifs were synthesized via polycondensation reactions. These polymers can fold into helical conformation different from their linear control. The chirality of helical conformation can further be tuned via acid–base complexation using chiral residues.

Graphical abstract: Helical polymers based on intramolecularly hydrogen-bonded aromatic polyamides

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Article information

DOI
https://doi.org/10.1039/C0CC03689G
Article type
Communication
Submitted
06 Sep 2010
Accepted
18 Oct 2010
First published
05 Nov 2010

Chem. Commun., 2010,46, 9019-9021

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Helical polymers based on intramolecularly hydrogen-bonded aromatic polyamides

Y. Lu, Z. Shi, Z. Li and Z. Guan, Chem. Commun., 2010, 46, 9019 DOI: 10.1039/C0CC03689G

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