Issue 48, 2010
From the journal:

Chemical Communications

Enantioselective total synthesis of cytotoxic taiwaniaquinones A and F†

Enrique Alvarez-Manzaneda,*a   Rachid Chahboun,a   Esteban Alvarez,a   Rubén Tapiaa  and  Ramón Alvarez-Manzanedab  

* Corresponding authors

a Departamento de Química Orgánica, Facultad de Ciencias, Instituto de Biotecnología, Universidad de Granada, 18071 Granada, Spain
E-mail: eamr@ugr.es
Fax: +34 958 24 80 89
Tel: +34 958 24 80 89

b Departamento de Química Orgánica, Facultad de Ciencias, Universidad de Almería, 04120 Almería, Spain

Abstract

The first synthesis of cytotoxic (−)-taiwaniaquinone A and (−)-taiwaniaquinone F has been achieved through the intramolecular aldol condensation of a ketoaldehyde and the oxidative cleavage of an isopropylidene ketal.

Graphical abstract: Enantioselective total synthesis of cytotoxic taiwaniaquinones A and F

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Article information

DOI
https://doi.org/10.1039/C0CC03763J
Article type
Communication
Submitted
09 Sep 2010
Accepted
08 Oct 2010
First published
01 Nov 2010

Chem. Commun., 2010,46, 9244-9246

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Enantioselective total synthesis of cytotoxic taiwaniaquinones A and F

E. Alvarez-Manzaneda, R. Chahboun, E. Alvarez, R. Tapia and R. Alvarez-Manzaneda, Chem. Commun., 2010, 46, 9244 DOI: 10.1039/C0CC03763J

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