Planar [Ni7] discs as double-bowl, pseudo metallacalix[6]arene host cavities

Seán T. Meally; Georgios Karotsis; Euan K. Brechin; Giannis S. Papaefstathiou; Peter W. Dunne; Patrick McArdle; Leigh F. Jones

doi:10.1039/B914538A

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Planar [Ni₇] discs as double-bowl, pseudometallacalix[6]arenehost cavities†

Seán T. Meally,^a Georgios Karotsis,^b Euan K. Brechin,^b Giannis S. Papaefstathiou,^c Peter W. Dunne,^a Patrick McArdle^a and Leigh F. Jones*^a

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* Corresponding authors

^a School of Chemistry, University Road, National University of Ireland, Galway, Ireland
E-mail: leigh.jones@nuigalway.ie
Tel: +353-091-49-3462

^b School of Chemistry, Joseph Black Building, University of Edinburgh, West Mains Road, Edinburgh, Scotland, UK

^c Laboratory of Inorganic Chemistry, Department of Chemistry, National and Kapodistrian University of Athens, Panepistimiopolis, Zografou, Greece

Abstract

We report three heptanuclear [Ni₇] complexes with planar disc-like cores, akin to double-bowl metallocalix[6]arenes, which form molecular H-bonded host cavities.

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Article information

DOI: https://doi.org/10.1039/B914538A
Article type: Communication
Submitted: 20 Jul 2009
Accepted: 19 Sep 2009
First published: 01 Oct 2009

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CrystEngComm, 2010,12, 59-63

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Planar [Ni₇] discs as double-bowl, pseudo metallacalix[6]arene host cavities

S. T. Meally, G. Karotsis, E. K. Brechin, G. S. Papaefstathiou, P. W. Dunne, P. McArdle and L. F. Jones, CrystEngComm, 2010, 12, 59 DOI: 10.1039/B914538A

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