Issue 12, 2010
From the journal:

CrystEngComm

Unusual complexes of trapped methanol with azacryptands†

Md. Alamgir Hossain,*a   Musabbir A. Saeed,a   Ganna Gryn'ova,b   Douglas R. Powellc  and  Jerzy Leszczynski*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, Jackson State University, 1325 J. R. Lynch Street, P.O. Box 17910, Jackson, MS, USA
E-mail: alamgir@chem.jsums.edu, jerzy@icnanotox.org
Fax: +1 601-979-3674
Tel: +1 601-979-3748

b Research School of Chemistry, Australian National University, Canberra, ACT, Australia

c Department of Chemistry and Biochemistry, University of Oklahoma, Norman, OK, USA

Abstract

Structural analysis of sulfate complexes of two different azacryptands crystallized under identical conditions in the presence of methanol and water reveals that one methanol is selectively trapped in each cavity, assisted by the specific arrangements of three external sulfates close to one tren unit.

Graphical abstract: Unusual complexes of trapped methanol with azacryptands

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Article information

DOI
https://doi.org/10.1039/C0CE00162G
Article type
Communication
Submitted
03 May 2010
Accepted
05 Aug 2010
First published
02 Sep 2010

CrystEngComm, 2010,12, 4042-4044

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Unusual complexes of trapped methanol with azacryptands

Md. A. Hossain, M. A. Saeed, G. Gryn'ova, D. R. Powell and J. Leszczynski, CrystEngComm, 2010, 12, 4042 DOI: 10.1039/C0CE00162G

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