A two dimensional heterospin layer coordination polymer of {[LCuIIGdIII(NO3)CuI2(CN)4]·MeOH}n with short CuI⋯CuI bonds

Peng-Fei Yan; Ying Wang; Peng Chen; Ju-Wen Zhang; Yan Wang; Guang-Ming Li

doi:10.1039/C0CE00207K

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

A two dimensional heterospin layer coordination polymer of {[LCu^IIGd^III(NO₃)Cu^I₂(CN)₄]·MeOH}_n with short Cu^I⋯Cu^I bonds†‡

Peng-Fei Yan,^a Ying Wang,^a Peng Chen,^a Ju-Wen Zhang,^a Yan Wang^a and Guang-Ming Li*^a

Author affiliations

* Corresponding authors

^a Key Laboratory of Functional Inorganic Materials Chemistry (MOE), School of Chemistry and Materials Science, Heilongjiang University, No. 74, Xuefu Road, Nangang District, Harbin, P. R. China

Abstract

Reaction of [LCu^IIGd^III(NO₃)₃] (L = N,N′-ethylenebis(salicylideneimine)) and [LiTCNE] (TCNE = tetracyanoethylene) in MeOH–CH₃CN affords an unexpected cyano-bridged coordination polymer {[LCu^IIGd^III(NO₃)Cu^I₂(CN)₄]·MeOH}_n (1) featuring unexpectedly short Cu^I⋯Cu^I bonds (2.470(2) Å). X-ray crystallographic analysis reveals that 1 possesses a two dimensional heterospin layer structure comprised of a chain of five-membered rings. The magnetic analysis of 1 reveals a ferromagnetic interaction between the Gd^III and Cu^II ions.

Download options Please wait...

Supplementary files

Crystal structure data TXT (23K)

Article information

DOI: https://doi.org/10.1039/C0CE00207K
Article type: Communication
Submitted: 17 May 2010
Accepted: 02 Sep 2010
First published: 05 Oct 2010

Download Citation

CrystEngComm, 2010,12, 4084-4086

Permissions

Request permissions

A two dimensional heterospin layer coordination polymer of {[LCu^IIGd^III(NO₃)Cu^I₂(CN)₄]·MeOH}_n with short Cu^I⋯Cu^I bonds

P. Yan, Y. Wang, P. Chen, J. Zhang, Y. Wang and G. Li, CrystEngComm, 2010, 12, 4084 DOI: 10.1039/C0CE00207K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

CrystEngComm