Issue 12, 2010
From the journal:

CrystEngComm

Mixed-metal complex [Fe(bipe)(Au(CN)2)2·MeOH] with goldclusters: a novel two-dimensional polyrotaxane net clipped by aurophilic interaction†

Haitao Xu,a   Gergely Juhász,b   Kazunari Yoshizawa,*b   Masashi Takahashi,c   Shinji Kanegawaa  and  Osamu Sato*a  

* Corresponding authors

a Kyushu University, Institute for Materials Chemistry and Engineering, 6-1 Kasuga-koen, kasuga, Fukuoka, Japan
E-mail: sato@cm.kyushu-u.ac.jp
Fax: +86 92-583-7787

b Kyushu University, Institute for Materials Chemistry and Engineering, Nishi-ku, Fukuoka, Japan
E-mail: kazunari@ms.ifoc.kyushu-u.ac.jp

c Toho University, Department of Chemistry, 2-2-1 Miyama, Funabashi, Chiba, Japan

Abstract

A novel two-dimensional mixed-metal coordination polymer, [Fe(bipe)(Au(CN)2)2·MeOH], composed of polyrotaxane with Fe2(bipe)2 loops and rigid [Au(CN)2]− rods, forms a 2D → 2D parallel interpenetrating structure. The two networks are clipped by gold clusters via aurophilic interaction.

Graphical abstract: Mixed-metal complex [Fe(bipe)(Au(CN)2)2·MeOH] with gold clusters: a novel two-dimensional polyrotaxane net clipped by aurophilic interaction

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Article information

DOI
https://doi.org/10.1039/C0CE00376J
Article type
Communication
Submitted
09 Apr 2010
Accepted
04 Aug 2010
First published
25 Aug 2010

CrystEngComm, 2010,12, 4031-4034

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Mixed-metal complex [Fe(bipe)(Au(CN)2)2·MeOH] with gold clusters: a novel two-dimensional polyrotaxane net clipped by aurophilic interaction

H. Xu, G. Juhász, K. Yoshizawa, M. Takahashi, S. Kanegawa and O. Sato, CrystEngComm, 2010, 12, 4031 DOI: 10.1039/C0CE00376J

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