Issue 12, 2010
From the journal:

CrystEngComm

A bifunctionalized porous material containing discrete assemblies of copper-porphyrins and calixarenes metallated by ion diffusion†

Rita De Zorzi,a   Nicol Guidolin,a   Lucio Randaccioa  and  Silvano Geremia*a  

* Corresponding authors

a Centre of Excellence in Biocrystallography, Department of Chemical Sciences, University of Trieste, Viale Giorgeri 1, Trieste, Italy
E-mail: sgeremia@units.it
Fax: +39 040 5583903
Tel: +39 040 5583936

Abstract

Nanoporous crystals of discrete stacks of metallo-porphyrins together with exogenous metal centers have been obtained by synergistic non-covalent interactions of tetra-cationic copper(II)-meso-tetrakis(4-N-methylpyridyl)porphyrin and polyanionic tetrasulfonato-tetrakis(hydroxylcarbonylmethoxy)calix[4]arene building blocks successively functionalized by diffusion and coordination of Zn2+ or Ni2+ ions.

Graphical abstract: A bifunctionalized porous material containing discrete assemblies of copper-porphyrins and calixarenes metallated by ion diffusion

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Article information

DOI
https://doi.org/10.1039/C0CE00440E
Article type
Communication
Submitted
16 Apr 2010
Accepted
11 Aug 2010
First published
08 Sep 2010

CrystEngComm, 2010,12, 4056-4058

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A bifunctionalized porous material containing discrete assemblies of copper-porphyrins and calixarenes metallated by ion diffusion

R. De Zorzi, N. Guidolin, L. Randaccio and S. Geremia, CrystEngComm, 2010, 12, 4056 DOI: 10.1039/C0CE00440E

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