Gold(I) derived thiosemicarbazone complexes with rare halogen–halogen interaction–reduction of [Au(damp-C1,N)Cl2]

Setshaba D. Khanye; Nikoletta B. Báthori; Gregory S. Smith; Kelly Chibale

doi:10.1039/B925037A

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Gold(i) derived thiosemicarbazone complexes with rare halogen–halogen interaction–reduction of [Au(damp-C¹,N)Cl₂]†

Setshaba D. Khanye,^a Nikoletta B. Báthori,^a Gregory S. Smith^a and Kelly Chibale*^ab

Author affiliations

* Corresponding authors

^a Department of Chemistry, University of Cape Town, Rondebosch 7701, Cape Town, South Africa
E-mail: Kelly.Chibale@uct.ac.za
Fax: +27 21 650 5195
Tel: +27 21 650 2553

^b Institute of Infectious Disease and Molecular Medicine, University of Cape Town, Rondebosch 7701, South Africa

Abstract

An attempt to prepare gold(III) complexes of thiosemicarbazones with the starting material gold(III) [Au(damp-C¹,N)Cl₂] led instead to gold(I) complexes with a rare Cl⋯Cl interaction.

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Article information

DOI: https://doi.org/10.1039/B925037A
Article type: Paper
Submitted: 27 Nov 2009
Accepted: 22 Dec 2009
First published: 29 Jan 2010

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Dalton Trans., 2010,39, 2697-2700

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Gold(I) derived thiosemicarbazone complexes with rare halogen–halogen interaction–reduction of [Au(damp-C¹,N)Cl₂]

S. D. Khanye, N. B. Báthori, G. S. Smith and K. Chibale, Dalton Trans., 2010, 39, 2697 DOI: 10.1039/B925037A

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Dalton Transactions