Issue 8, 2010
From the journal:

Dalton Transactions

Rhodium-P,O-bidentate coordinated ureaphosphine ligands for asymmetric hydrogenation reactions†

Jurjen Meeuwissen,a   Remko J. Detz,b   Albertus J. Sandee,ac   Bas de Bruina  and  Joost N. H. Reek*a  

* Corresponding authors

a Homogeneous and Supramolecular Catalysis, Van't Hoff Institute for Molecular Sciences, Nieuwe Achtergracht 166, Amsterdam, The Netherlands
E-mail: j.n.h.reek@uva.nl
Fax: (+31) (0)20 5255604

b InCatT B.V., Roetersstraat 35, Amsterdam, The Netherlands
E-mail: remko.detz@incatt.nl

c BASF Nederland B.V. Catalysts, Strijkviertel 67, De Meern, The Netherlands

Abstract

We present new ureaphosphine ligands that coordinate in a P,O-bidentate fashion to rhodium(I). The ureaphosphine-Rh(I)-complexes were effectively used in the asymmetric hydrogenation of cyclic enamides giving high conversions and enantioselectivity.

Graphical abstract: Rhodium-P,O-bidentate coordinated ureaphosphine ligands for asymmetric hydrogenation reactions

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Article information

DOI
https://doi.org/10.1039/B926043A
Article type
Communication
Submitted
09 Dec 2009
Accepted
17 Dec 2009
First published
06 Jan 2010

Dalton Trans., 2010,39, 1929-1931

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Rhodium-P,O-bidentate coordinated ureaphosphine ligands for asymmetric hydrogenation reactions

J. Meeuwissen, R. J. Detz, A. J. Sandee, B. de Bruin and J. N. H. Reek, Dalton Trans., 2010, 39, 1929 DOI: 10.1039/B926043A

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