3d–4f Clusters with large spin ground states and SMM behaviour

Viswanathan Baskar; Kandasamy Gopal; Madeleine Helliwell; Floriana Tuna; Wolfgang Wernsdorfer; Richard E. P. Winpenny

doi:10.1039/B927114G

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3d–4f Clusters with large spin ground states and SMM behaviour†‡

Viswanathan Baskar,^a Kandasamy Gopal,^a Madeleine Helliwell,^a Floriana Tuna,^a Wolfgang Wernsdorfer^b and Richard E. P. Winpenny*^ac

Author affiliations

* Corresponding authors

^a School of Chemistry, The University of Manchester, Oxford Road, Manchester, UK
E-mail: richard.winpenny@manchester.ac.uk

^b Laboratoire Louis Néel - CNRS, BP 166, 25 Avenue des Martyrs, Grenoble Cedex 9, France

^c The Photon Science Institute, The University of Manchester, Oxford Road, Manchester, UK

Abstract

Three new Cu–Ln cage complexes bridged by phosphonates and acetates are reported; one—a Cu₂₄Dy₈ cage—is a new single molecule magnet (SMM).

This article is part of the themed collections: Molecular magnets and Collection of articles dedicated to Professor David W. H. Rankin on the occasion of his retirement

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DOI: https://doi.org/10.1039/B927114G
Article type: Communication
Submitted: 22 Dec 2009
Accepted: 25 Mar 2010
First published: 12 Apr 2010

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Dalton Trans., 2010,39, 4747-4750

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3d–4f Clusters with large spin ground states and SMM behaviour

V. Baskar, K. Gopal, M. Helliwell, F. Tuna, W. Wernsdorfer and R. E. P. Winpenny, Dalton Trans., 2010, 39, 4747 DOI: 10.1039/B927114G

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Dalton Transactions

3d–4f Clusters with large spin ground states and SMM behaviour†‡

Abstract

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3d–4f Clusters with large spin ground states and SMM behaviour

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