(η6-Arene) ruthenium(II) complexes and metallo-papain hybrid as Lewis acid catalysts of Diels–Alder reaction in water

Barisa Talbi; Pierre Haquette; Annie Martel; Frédéric de Montigny; Céline Fosse; Stéphane Cordier; Thierry Roisnel; Gérard Jaouen; Michèle Salmain

doi:10.1039/C001630F

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(η⁶-Arene) ruthenium(ii) complexes and metallo-papain hybrid as Lewis acid catalysts of Diels–Alder reaction in water†

Barisa Talbi,^a Pierre Haquette,^a Annie Martel,^a Frédéric de Montigny,^a Céline Fosse,^b Stéphane Cordier,^c Thierry Roisnel,^c Gérard Jaouen^a and Michèle Salmain*^a

Author affiliations

* Corresponding authors

^a Chimie ParisTech (Ecole Nationale Supérieure de Chimie de Paris), Laboratoire Charles Friedel, CNRS UMR 7223, 11 rue Pierre et Marie Curie, Paris cedex 05, France
E-mail: michele-salmain@chimie-paristech.fr
Fax: +33 1 43260061
Tel: +33 144276732

^b Chimie ParisTech (Ecole Nationale Supérieure de Chimie de Paris), Laboratoire de spectrométrie de masse, 11 rue Pierre et Marie Curie, Paris cedex 05, France

^c Université de Rennes 1, UMR CNRS 6226 “Sciences Chimiques de Rennes”, avenue du Général Leclerc, Rennes cedex, France

Abstract

Covalent embedding of a (η⁶-arene) ruthenium(II) complex into the protein papain gives rise to a metalloenzyme displaying a catalytic efficiency for a Lewis acid-mediated catalysed Diels–Alder reaction enhanced by two orders of magnitude in water.

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Article information

DOI: https://doi.org/10.1039/C001630F
Article type: Communication
Submitted: 25 Jan 2010
Accepted: 22 Mar 2010
First published: 20 Apr 2010

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Dalton Trans., 2010,39, 5605-5607

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(η⁶-Arene) ruthenium(II) complexes and metallo-papain hybrid as Lewis acid catalysts of Diels–Alder reaction in water

B. Talbi, P. Haquette, A. Martel, F. de Montigny, C. Fosse, S. Cordier, T. Roisnel, G. Jaouen and M. Salmain, Dalton Trans., 2010, 39, 5605 DOI: 10.1039/C001630F

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